Reversible pressure-induced polymerization of Fe(C5H5)2 doped C70

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Reversible pressure - induced polymerization of Fe ( C

High pressure Raman, IR and X-ray diffraction (XRD) studies have been carried out on C 70 (Fe(C 5 H 5) 2) 2 (hereafter, " C 70 (Fc) 2 ") sheets. Theoretical calculation is further used to analyze the Electron Localization Function (ELF) and charge transfer in the crystal and thus to understand the transformation of C 70 (Fc) 2 under pressure. Our results show that even at room temperature dimer...

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ژورنال

عنوان ژورنال: Carbon

سال: 2013

ISSN: 0008-6223

DOI: 10.1016/j.carbon.2013.06.032